Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes
2010; American Chemical Society; Volume: 132; Issue: 27 Linguagem: Inglês
10.1021/ja104177w
ISSN1943-2984
AutoresVerónica López‐Carrillo, Antonio M. Echavarren,
Tópico(s)Cyclopropane Reaction Mechanisms
ResumoThe gold(I)-catalyzed intermolecular reaction of terminal alkynes with alkenes leads to cyclobutenes. The use of sterically hindered cationic Au(I) complexes as catalysts is key for the success of this reaction.
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