Artigo Revisado por pares

Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes

2010; American Chemical Society; Volume: 132; Issue: 27 Linguagem: Inglês

10.1021/ja104177w

ISSN

1943-2984

Autores

Verónica López‐Carrillo, Antonio M. Echavarren,

Tópico(s)

Cyclopropane Reaction Mechanisms

Resumo

The gold(I)-catalyzed intermolecular reaction of terminal alkynes with alkenes leads to cyclobutenes. The use of sterically hindered cationic Au(I) complexes as catalysts is key for the success of this reaction.

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