Synthesis and Characterization of (MesGaO) 9 (Mes = Me 3 C 6 H 2 ) and Crystal Structure of the First Galloxane Comparable to Catalytically Active Aluminum Compounds
1997; American Chemical Society; Volume: 16; Issue: 13 Linguagem: Inglês
10.1021/om970086d
ISSN1520-6041
AutoresJens Storre, A. Klemp, Herbert W. Roesky, Roland Fleischer, Dietmar Stalke,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoThe thermolysis of (Mes2GaOH)2·THF in toluene or 1,4-dioxane at 100 °C resulted in the formation of (MesGaO)9 (1). A byproduct of this reaction is Mes3Ga. Compound 1 was characterized by electron impact mass spectroscopy and single-crystal X-ray structural analysis. The structure consists of two six-membered (MesGaO)3 rings connected by three μ2-(MesGaO) units.
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