Is the [9]Annulene Cation a Möbius Annulene?
2009; Wiley; Volume: 48; Issue: 52 Linguagem: Inglês
10.1002/anie.200900886
ISSN1521-3773
AutoresGötz Bucher, Stefan Grimme, Robert Huenerbein, Alexander A. Auer, E. Mucke, Felix Köhler, Jan Siegwarth, Rainer Herges,
Tópico(s)Photochemistry and Electron Transfer Studies
ResumoAngewandte Chemie International EditionVolume 48, Issue 52 p. 9971-9974 Communication Is the [9]Annulene Cation a Möbius Annulene?† Götz Bucher Dr., Götz Bucher Dr. [email protected] Ruhr-Universität Bochum, Organische Chemie II, Universitätsstrasse 150 (Germany) Current address: WestCHEM Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow G12 8QQ (UK)Search for more papers by this authorStefan Grimme Prof., Stefan Grimme Prof. [email protected] Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)Search for more papers by this authorRobert Huenerbein, Robert Huenerbein Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)Search for more papers by this authorAlexander A. Auer Dr., Alexander A. Auer Dr. [email protected] Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237 Düsseldorf (Germany)Search for more papers by this authorEva Mucke, Eva Mucke Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorFelix Köhler Dr., Felix Köhler Dr. Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorJan Siegwarth Dr., Jan Siegwarth Dr. Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorRainer Herges Prof. Dr., Rainer Herges Prof. Dr. [email protected] Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this author Götz Bucher Dr., Götz Bucher Dr. [email protected] Ruhr-Universität Bochum, Organische Chemie II, Universitätsstrasse 150 (Germany) Current address: WestCHEM Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow G12 8QQ (UK)Search for more papers by this authorStefan Grimme Prof., Stefan Grimme Prof. [email protected] Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)Search for more papers by this authorRobert Huenerbein, Robert Huenerbein Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)Search for more papers by this authorAlexander A. Auer Dr., Alexander A. Auer Dr. [email protected] Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237 Düsseldorf (Germany)Search for more papers by this authorEva Mucke, Eva Mucke Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorFelix Köhler Dr., Felix Köhler Dr. Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorJan Siegwarth Dr., Jan Siegwarth Dr. Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this authorRainer Herges Prof. Dr., Rainer Herges Prof. Dr. [email protected] Otto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, 24118 Kiel (Germany)Search for more papers by this author First published: 15 December 2009 https://doi.org/10.1002/anie.200900886Citations: 27 † This work was supported by the Deutsche Forschungsgemeinschaft (DFG). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Does it do the twist? High-level theoretical calculations show that the [9]annulene cation exists in two isomers: a twisted 4n electron Möbius aromatic compound, and a non-twisted boat-like Hückel conformation (see scheme). The latter form was detected by laser flash photolysis experiments; an example of a stable, charged, or uncharged parent Möbius annulene is still elusive. References 1 1aH. S. Rzepa, Chem. Rev. 2005, 105, 3697– 3715; 1bR. Herges, Chem. Rev. 2006, 106, 4820– 4842. 2E. 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Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200900886_sm_miscellaneous_information.pdf178.7 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume48, Issue52December 21, 2009Pages 9971-9974 ReferencesRelatedInformation
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