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Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst

2005; Royal Society of Chemistry; Issue: 29 Linguagem: Inglês

10.1039/b506426k

ISSN

1364-548X

Autores

Richard L. Brutchey, Ian J. Drake, Alexis T. Bell, T. Don Tilley,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP) via an H-atom transfer mechanism.

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