Data composites of airborne observations of tropospheric ozone and its precursors
2000; American Geophysical Union; Volume: 105; Issue: D16 Linguagem: Inglês
10.1029/2000jd900232
ISSN2156-2202
AutoresL. K. Emmons, Didier Hauglustaine, Jean‐François Müller, Mary Anne Carroll, Guy Brasseur, Dominik Brunner, J. Staehelin, V. Thouret, A. Marenco,
Tópico(s)Atmospheric and Environmental Gas Dynamics
ResumoJournal of Geophysical Research: AtmospheresVolume 105, Issue D16 p. 20497-20538 Composition and ChemistryFree Access Data composites of airborne observations of tropospheric ozone and its precursors Louisa K. Emmons, Louisa K. EmmonsSearch for more papers by this authorDidier A. Hauglustaine, Didier A. HauglustaineSearch for more papers by this authorJean-François Müller, Jean-François MüllerSearch for more papers by this authorMary Anne Carroll, Mary Anne CarrollSearch for more papers by this authorGuy P. Brasseur, Guy P. BrasseurSearch for more papers by this authorDominik Brunner, Dominik BrunnerSearch for more papers by this authorJohannes Staehelin, Johannes StaehelinSearch for more papers by this authorValerie Thouret, Valerie ThouretSearch for more papers by this authorAlain Marenco, Alain MarencoSearch for more papers by this author Louisa K. Emmons, Louisa K. EmmonsSearch for more papers by this authorDidier A. Hauglustaine, Didier A. HauglustaineSearch for more papers by this authorJean-François Müller, Jean-François MüllerSearch for more papers by this authorMary Anne Carroll, Mary Anne CarrollSearch for more papers by this authorGuy P. Brasseur, Guy P. BrasseurSearch for more papers by this authorDominik Brunner, Dominik BrunnerSearch for more papers by this authorJohannes Staehelin, Johannes StaehelinSearch for more papers by this authorValerie Thouret, Valerie ThouretSearch for more papers by this authorAlain Marenco, Alain MarencoSearch for more papers by this author First published: 01 August 2000 https://doi.org/10.1029/2000JD900232Citations: 155AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Abstract Tropospheric data from a number of aircraft campaigns have been gridded onto global maps, forming "data composites" of chemical species important in ozone photochemistry. Although these are not climatologies in the sense of a long temporal average, these data summaries are useful for providing a picture of the global distributions of these species and are a start to creating observations-based climatologies. Using aircraft measurements from a number of campaigns, we have averaged observations of O3, CO, NO, NOx, HNO3, PAN, H2O2, CH3OOH, HCHO, CH3COCH3, C2H6, and C3H8 onto a 5° latitude by 5° longitude horizontal grid with a 1-km vertical resolution. These maps provide information about the distributions at various altitudes, but also clearly show that direct observations of the global troposphere are still very limited. A set of regions with 10°–20° horizontal extent has also been chosen wherein there is sufficient data to study vertical profiles. These profiles are particularly valuable for comparison with model results, especially when a full suite of chemical species can be compared simultaneously. The O3 and NO climatologies generated from measurements obtained during commercial aircraft flights associated writh the MOZAIC and NOXAR programs are incorporated with the data composites at 10–11 km. As an example of the utility of these data composites, observations are compared to results from two global chemical transport models, MOZART and IMAGES, to help identify incorrect emission sources, incorrect strength of convection, and missing chemistry in the models. These comparisons suggest that in MOZART the NOx biomass burning emissions may be too low and convection too weak and that the transport of ozone from the stratosphere in IMAGES is too great. The ozone profiles from the data composites are compared with ozonesonde climatologies and show that in some cases the aircraft data agree with the long-term averages, but in others, such as in the western Pacific during PEM-Tropics-A, agreement is lacking. Finally, the data composites provide temporal and spatial information, which can help identify the locations and seasons where new measurements would be most valuable. All of the data composites presented here are available via the Internet (http://aoss.engin.umich.edu/SASSarchive/). References Anderson, B. E., G. L. Gregory, J. D. W. Barrick, J. E. Collins Jr., G. W. Sachse, D. Bagwell, M. C. Shipham, J. D. Bradshaw, S. T. Sandholm, The impact of U.S. continental outflow on ozone and aerosol distributions over the western Atlantic, J. Geophys. Res., 98, 23477– 23489, 1993a. Anderson, B. E., G. L. Gregory, J. D. W. Barrick, J. E. Collins, G. W. Sachse, C. H. Hudgins, J. D. Bradshaw, S. T. 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