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Quantitative Study of Be(II) Complexation by Soil Fulvic Acids by Molecular Fluorescence Spectroscopy

1996; American Chemical Society; Volume: 30; Issue: 11 Linguagem: Inglês

10.1021/es9507022

1520-5851

Joaquim C. G. Esteves da Silva, Adélio A. S. C. Machado, María A. Ramos, Florencio Arce, Francisco Rey,

Radioactive element chemistry and processing

The interaction of the beryllium ion [Be(II)] with one of the major constituent of soil organic matter, fulvic acids (fua), was investigated. The complexation of Be(II) by two samples of fua (amph and gran), at a concentration of 80 mg/L, was monitored by synchronous fluorescence spectroscopy at four pH values (4, 5, 6, and 7). A self-modeling curve resolution technique (evolving factor analysis) was used in the analysis of the sets of spectra collected at increasing Be(II):fua ratio to obtain concentration profiles that ideally correspond to one type of binding site. These profiles were adjusted to a 1:1 complexation model. Quite strong complexation of Be(II) by fua occurs at nearly neutral pH (6−7) (logarithm of the conditional stability constant between 5.6 and 6.5), indicating that fua probably affect markedly the mobility of Be(II) in the environment.