Mixed‐Metal Cluster Formation Carbonylmetalate‐Induced Pt‐P Bond Cleavage in [PtCl 2 (Ph 2 PCH 2 PPh 2 )]
1987; Wiley; Volume: 26; Issue: 1 Linguagem: Inglês
10.1002/anie.198700881
ISSN1521-3773
AutoresPierre Braunstein, Nicolas Guarino, Claude de Bellefon, Jean‐Luc Richert,
Tópico(s)Ferrocene Chemistry and Applications
ResumoPh2PCH2PPh2 bridges the metal centers in the heterometal clusters that are formed via partial ligand migration upon reaction of the title compound with carbonylmetalates such as [Mn(CO)5]⊖. Reaction with [Na2Fe(CO)8] leads, inter alia, to the formation of the cluster 1. The reactions confirm that the lability of the PtP bond suffices for the synthesis of clusters
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