Microbial resolution of organometallic planar chirality. Enantioselective reduction of orto- and meta-substituted tricarbonylchromium benzaldehydes by bakers' yeast
1991; Elsevier BV; Volume: 413; Issue: 1-3 Linguagem: Inglês
10.1016/0022-328x(91)80043-j
ISSN1872-8561
AutoresSiden Top, Gérard Jaoeun, Clara Baldoli, Paola Del Buttero, Stefano Maiorana,
Tópico(s)Chemical Synthesis and Analysis
Resumoortho- and meta-substituted (η-benzaldehyde)tricarbonylchromium(0) complexes can be enantioselectively reduced by commercial bakers' yeast to give alcohols and unchanged aldehydes with good to high enantiomeric excesses.
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