Structure of carbanions having carbocations as counterions
1993; Royal Society of Chemistry; Issue: 20 Linguagem: Inglês
10.1039/c39930001558
ISSN2050-5639
AutoresManfred T. Reetz, Carsten Bingel, Klaus Harms,
Tópico(s)Structural and Chemical Analysis of Organic and Inorganic Compounds
ResumoThe first X-ray structural analysis of a carbanion having a carbocation as the counterion, [EtC(CO2Me)2]–C[(NMe2)3]+ is reported, showing unusual hydrogen bonding between the carbanion and the methyl groups of the carbocation.
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