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Metal–organic frameworks as a very suitable reaction inductor for selective solvent-free multicomponent reaction: IRMOF-3 as a heterogeneous nanocatalyst for Kabachnik–Fields three-component reaction

2013; Elsevier BV; Volume: 179; Linguagem: Inglês

10.1016/j.micromeso.2013.05.009

1873-3093

Sadegh Rostamnia, Hongchuan Xin, Nasrin Nouruzi,

Synthesis and Characterization of Heterocyclic Compounds

IRMOF-3 is found to be an active, selective and stable solid catalyst for three-component, one-pot reaction of amines, aldehydes and dimethyl phosphite to form the corresponding α-aminophosphonates in high yields. The catalyst can be isolated from the reaction mixture and reused at least four times.