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The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙–, Cu2+ and Gd3+)

2002; Royal Society of Chemistry; Issue: 15 Linguagem: Inglês

10.1039/b202628g

1364-548X

Augustin M. Mădălan, Herbert W. Roesky, Marius Andruh, Mathias Noltemeyer, Nicolae Stanică,

Organic and Molecular Conductors Research

A novel heterospin system, [(CuL)2Gd(TCNQ)2].TCNQ-.CH3OH.2CH3CN, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato ions with anionic organic radicals.