Preparation of titanium pentamethylcyclopentadienyl trialkyls and crystal structure of tribenzylpentamethylcyclopentadienyltitanium, showing some evidence of a CH2? Ti interaction
1986; Royal Society of Chemistry; Issue: 14 Linguagem: Inglês
10.1039/c39860001118
ISSN2050-5639
AutoresMiguel Mena, María Angela Pellinghelli, Pascual Royo, Ricardo Serrano, António Tiripicchio,
Tópico(s)Coordination Chemistry and Organometallics
ResumoTitanium pentamethylcyclopentadienyl trialkyls (η5-C5Me5)TiR3(R = Me, CH2SiMe3, C6F5, and CH2Ph) are easily obtained by conventional alkylation of the trichloro analogue; the structure of the tribenzyl derivative, determined by X-ray methods, shows some evidence of a CH2⋯ Ti interaction.
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