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BIBTEX RIS

The synthesis of tris(perfluoroalkyl)phosphines

2005; Royal Society of Chemistry; Issue: 35 Linguagem: Inglês

10.1039/b507752d

ISSN

1364-548X

Autores

M.B. Murphy-Jolly, Lesley C. Lewis, Andrew J. M. Caffyn,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.

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