Transition‐Metal Complexes with Bidentate Ligands Spanning trans ‐Positions. Part XVII. Some platinum(II) complexes with anionic ligands such as methoxide, formate, carboxylate, hydride, and borohydride, and the X‐ray crystal structure of [PtHCl()] (PP = 2,11‐bis(diphenylphosphinomethyl)benzo[ c ]phenanthrene)
1988; Wiley; Volume: 71; Issue: 6 Linguagem: Inglês
10.1002/hlca.19880710608
ISSN1522-2675
AutoresGustav Bracher, B. Kellenberger, Luigi M. Venanzi, F. Bachechi, L. Zambonelli,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoAbstract The complexes trans ‐[PtXY( 2 ] (X = H or Me; Y = OMe, OCHO, CO 2 H, and BH 4 ; 2 = 2,11‐bis{bis[3‐(trifluoromethyl)phenyl]phosphinomethyl}benzo[ c ]phenanthrene) were prepared, and their decompositions to trans [PtHX( 2 )] were studied. Some binuclear hydrido‐bridged complexes, e.g. [( 2 )HPt(μ‐H)PtH( 2 )] + , were also obtained. The preparation of complexes trans ‐[PtHX( 28 ) 2 ] (X = H or Me, 28 = bis[3‐(trifluoromethyl)phenyl]benzylphosphine) is also reported. The X‐ray crystal structure of trans ‐[PtHCl 1 )] ( 1 = 2,11‐bis(diphenylphosphinomethyl)benzo[ c ]phenanthrene) was carried out.
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