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A Metal–Organic Framework as Attractive Cryogenic Magnetorefrigerant

2012; Wiley; Volume: 18; Issue: 41 Linguagem: Inglês

10.1002/chem.201200861

1521-3765

Romain Sibille, Thomas Mazet, B. Malaman, Michel François,

Metal-Organic Frameworks: Synthesis and Applications

Magnetocaloric effect: A GdIII-based metal–organic framework (MOF) has an unprecedented large magnetocaloric effect around 2 K. It was shown to be an interesting magnetorefrigerant for ultralow-temperature applications, because it combines the advantages of molecular materials and the robustness of a framework with strong 3D chemical connections (see figure). Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.