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Supercapacitors Based on Metal Electrodes Prepared from Nanoparticle Mixtures at Room Temperature

2010; American Chemical Society; Volume: 1; Issue: 9 Linguagem: Inglês

10.1021/jz1004076

1948-7185

Hideyuki Nakanishi, Bartosz A. Grzybowski,

Advanced battery technologies research

Films comprising Au and Ag nanoparticles are transformed into porous metal electrodes by desorption of weak organic ligands followed by wet chemical etching of silver. Thus prepared electrodes provide the basis for supercapacitors whose specific capacitances approach 70 F/g. Cyclic voltammetry measurement yield "rectangular" I−V curves even at high scan rates, indicating that the supercapacitors have low internal resistance. Owing to this property, the supercapacitors have a high power density ∼12 kW/kg, comparable with that of the state-of-the-art carbon-based devices. The entire assembly protocol does not require high-temperature processing or the use of organic binders.