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Satellite structure in the photoelectron spectra of the core electrons of NO, N2O and H2O

1975; Elsevier BV; Volume: 6; Issue: 5 Linguagem: Inglês

10.1016/0368-2048(75)80028-4

1873-2526

David P. Spears, H. J. Fischbeck, Thomas A. Carlson,

Catalytic Processes in Materials Science

Abstract Satellite structures have been observed in the photoelectron spectra of the core shells of nitric oxide, nitrous oxide and water. An attempt has been made to characterize the satellite structure in terms of monopole transitions resulting from electron shake-up. For this purpose comparisons of the observed excitation energies were made with optical data for both (1) the neutral molecules and (2) the analogous equivalent-core molecular ions. Using these energy comparisons and population densities for various molecular orbitals some assignments are made of the orbitals involved in electron shake-up as a function of the core vacancy.