Preparation of π-deficient heteroarylzinc halides by oxidative addition of active zinc and its palladium-catalyzed reaction
1993; Elsevier BV; Volume: 49; Issue: 43 Linguagem: Inglês
10.1016/s0040-4020(01)80174-5
ISSN1464-5416
AutoresTakao Sakamoto, Yoshinori Kondo, Naoko Murata, Hiroshi Yamanaka,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoThe oxidative addition of active zinc to iodo- and bromo-substituted π-deficient heteroarenes such as pyridine, pyrimidine, and quinoline gave the corresponding heteroarylzinc halides which were transformed to the arylated and benzoylated derivatives by palladium-catalyzed reaction.
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