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The sorption and crystallographic characteristics of alumina activated in a reactor for pneumatic transport

2006; Serbian Chemical Society; Volume: 71; Issue: 11 Linguagem: Inglês

10.2298/jsc0611237r

1820-7421

Ljiljana Rožić, Tatjana Novaković, Srdjan Petrović, Željko Čupić, Željko Grbavčić, Aleksandar Rosic,

Zeolite Catalysis and Synthesis

Active transition alumina powders were obtained by flash calcination of gibbsite in a reactor for pneumatic transport in the dilute, two-phase flow regime in the temperature interval from 883 to 943 K with a residence time between 0.4 and 0.9 s. The results of X-ray diffraction analysis confirmed that the activated alumina samples were either microcrystalline or amorphous. From nitrogen adsorption-desorption isotherms, the specific surface areas of all samples were calculated by the BET method. Using the sorption data, the fractal dimension of the surface of the alumina samples was calculated according to a modified FHH method. By application of fractal geometry, using the values of the fractal dimension of the surface and of the specific surface area, the effective surface areas of the active aluminas were calculated for the adsorption of molecules having a cross-section area greater than that of the nitrogen molecule.