Artigo Acesso aberto Revisado por pares

Carbonylation Reaction of Isoprene Catalyzed by Palladium(II) Acetate and Triphenylphosphine

1977; Oxford University Press; Volume: 50; Issue: 2 Linguagem: Inglês

10.1246/bcsj.50.553

ISSN

1348-0634

Autores

Jiro Tsuji, Hideyuki Yasuda,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

The carbonylation reaction of isoprene in alcohol catalyzed by palladium(II) acetate and triphenylphosphine gave 4-methyl-3-pentenoate selectively in a moderate yield. Unlike butadiene, no dimerization-carbonylation of isoprene to give C11 esters took place.

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