Synthesis of a solvent-sensitive highly fluorescent derivative of perfluorocyclopentene
2007; Elsevier BV; Volume: 48; Issue: 43 Linguagem: Inglês
10.1016/j.tetlet.2007.08.086
ISSN1873-3581
AutoresZhanxian Li, Wei Sun, Yan‐Feng Yue, Ming‐Hua Zheng, Chun‐Hu Xu, Jingyi Jin, Chen‐Jie Fang, Chun‐Hua Yan,
Tópico(s)Fluorine in Organic Chemistry
ResumoA solvent-sensitive highly fluorescent compound, N-[2-(1′,3′,4′,4′,5′,5′-hexafluorocyclopentenyl)]-4-(5-methoxy-thiazolyl)pyridine (1D) was synthesized as an unexpected product of the reaction of 4-bromo-5-methoxy-2-(4-pyridyl)thiazole (1B) with perfluorocyclopentene in the presence of n-BuLi. Primary mechanism of this reaction was proposed, and the photophysical properties of 1D in different solvents were studied.
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