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Stereochemistry of Halogen-Metal Exchange Reaction of Vinyl Halide with Grignard Reagent

1984; Oxford University Press; Volume: 57; Issue: 8 Linguagem: Inglês

10.1246/bcsj.57.2319

1348-0634

Toshio Sugita, Yo-ichi Sakabe, Toshiaki Sasahara, Mitsunori Tsukada, Katsuhiko Ichikawa,

Inorganic and Organometallic Chemistry

Abstract Halogen-magnesium exchange was confirmed to proceed with stereospecific retention of configuration in the reaction of β-bromostyrene and butylmagnesium bromide.