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Pentastrontium Tris[tetraoxovanadate(V)]catena-Monoxocuprate(I), Sr5(VO4)3(CuO) - An Apatite Derivative with Inserted Linear1Ë[CuO]1- Chains

1999; Wiley; Volume: 625; Issue: 2 Linguagem: Inglês

10.1002/(sici)1521-3749(199902)625

1521-3749

W. Carrillo‐Cabrera, Hans Georg̀ von Schnering,

Radioactive element chemistry and processing

Zeitschrift für anorganische und allgemeine ChemieVolume 625, Issue 2 p. 183-185 Short Communication Pentastrontium Tris[tetraoxovanadate(V)] catena-Monoxocuprate(I), Sr5(VO4)3(CuO) – An Apatite Derivative with Inserted Linear 1Ë[CuO]1– Chains Wilder Carrillo-Cabrera, Wilder Carrillo-Cabrera Stuttgart, Max-Planck-Institut für FestkörperforschungSearch for more papers by this authorHans Georg von Schnering, Corresponding Author Hans Georg von Schnering Stuttgart, Max-Planck-Institut für FestkörperforschungProf. Dr. Dres. h.c. H. G. von Schnering, Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 StuttgartSearch for more papers by this author Wilder Carrillo-Cabrera, Wilder Carrillo-Cabrera Stuttgart, Max-Planck-Institut für FestkörperforschungSearch for more papers by this authorHans Georg von Schnering, Corresponding Author Hans Georg von Schnering Stuttgart, Max-Planck-Institut für FestkörperforschungProf. Dr. Dres. h.c. H. G. von Schnering, Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 StuttgartSearch for more papers by this author First published: 24 February 1999 https://doi.org/10.1002/(SICI)1521-3749(199902)625:2 3.0.CO;2-6Citations: 27AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Abstract Sr5(VO4)3(CuO) was prepared via solid state reactions from mixed powders of the metal oxides or carbonates in corundum crucibles in air (1173–1740 K). The compound is transparent and stable in air. The color changes with the preparation temperature from light gray (1173 K) to gray (1740 K). The crystal structure (space group P63/m, No. 176; Z = 2; a = 10.126 Å, c = 7.415 Å) is a derivative of the apatite Ca5(PO4)3OH, and is characterized by isolated [VO4]3– anions (d(V–O) = 1.710 Å) and infinite linear 1∞[CuO]1– chains (d(Cu–O) = 1.854 Å) inserted in the channels parallel to the hexagonal axis. The compound prepared at 1740 K contains vacancies at the copper and oxygen positions of the linear chains (about 10% and 5%, respectively). Citing Literature Volume625, Issue2February, 1999Pages 183-185 RelatedInformation