Voltar
Artigo Revisado por pares
BIBTEX RIS

Synthesis, some reactions, and molecular structure of the Pd(BF4)2 complex of 1,1′-bis(diphenylphosphino)ferrocene

1993; Elsevier BV; Volume: 458; Issue: 1-2 Linguagem: Inglês

10.1016/0022-328x(93)80474-p

ISSN

1872-8561

Autores

Masaru Satô, Hiroaki Shigeta, Masato Sekino, Sadatoshi Akabori,

Tópico(s)

Marine Sponges and Natural Products

Resumo

1,1′-Bis(diphenylphosphino)ferrocene (dppf) reacted with [Pd(CH3CN)4](BF4)2 in the presence of one equivalent of phosphines to give a stable 1/1 complex in which there is a bonding interaction between Fe and Pd atoms. An X-ray structure determination of [(dppf)Pd(PPh3)](BF4)2 confirms the presence of a dative bond (2.877(2) Å. In the case of ligands other than phosphines, no complex with a metal-metal bond was obtained.

Referência(s)