Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes
2001; Elsevier BV; Volume: 42; Issue: 26 Linguagem: Inglês
10.1016/s0040-4039(01)00758-4
ISSN1873-3581
AutoresJordi Cortès, Marcial Moreno‐Mañas, Roser Pleixats,
Tópico(s)Metal-Catalyzed Oxygenation Mechanisms
ResumoThe preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate.
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