Structural characterization and cytotoxicity studies of ruthenium(II)–dmso–chloro complexes of chalcone and flavone derivatives
2009; Elsevier BV; Volume: 29; Issue: 3 Linguagem: Inglês
10.1016/j.poly.2009.11.012
ISSN1873-3719
AutoresRishikesh Prajapati, Santosh Kumar Dubey, Ruchi Gaur, Raj Kumar Koiri, Brajesh Kumar Maurya, Surendra Kumar Trigun, Lallan Mishra,
Tópico(s)Synthesis of Organic Compounds
ResumoA synthetic precursor cis-[RuIICl2(dmso)4] is complexed separately with 3-(4-benzyloxyphenyl)-1-(2-hydroxylphenyl)-prop-2-en-1-one (L1H) and 2-(4-benzyloxyphenyl)-3hydroxy-chromen-4-one (L2H). The resulting complexes are assigned the composition fac-[RuCl(S-dmso)3(L1)] 1 and fac-[RuCl(S-dmso)3(L2)] 2 using elemental analyses, FAB mass data and spectroscopic (IR, 1H NMR, UV–Vis, emission) spectral properties. The X-ray diffraction analysis shows that complexes self-associate through non-covalent interactions and provide 1D and 2D supramolecular structures. These complexes are assayed for their cytotoxicity studies on Dalton Lymphoma cell lines.
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