Highly Luminescent Cu I Complexes for Light‐Emitting Electrochemical Cells
2006; Volume: 18; Issue: 10 Linguagem: Inglês
10.1002/adma.200502365
ISSN1521-4095
AutoresNicola Armaroli, Gianluca Accorsi, Michel Holler, Omar Moudam, Jean‐François Nierengarten, Zhongyuan Zhou, R. T. Wegh, R. Welter,
Tópico(s)Lanthanide and Transition Metal Complexes
ResumoAdvanced MaterialsVolume 18, Issue 10 p. 1313-1316 Communication Highly Luminescent CuI Complexes for Light-Emitting Electrochemical Cells† N. Armaroli, N. Armaroli armaroli@isof.cnr.it Molecular Photoscience Group, Istituto per la Sintesi Organica e la Fotoreattività del CNR, Via Gobetti 101, 40129 Bologna, ItalySearch for more papers by this authorG. Accorsi, G. Accorsi Molecular Photoscience Group, Istituto per la Sintesi Organica e la Fotoreattività del CNR, Via Gobetti 101, 40129 Bologna, ItalySearch for more papers by this authorM. Holler, M. Holler Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur et CNRS, 25 rue Becquerel, 67087 Strasbourg Cedex 2, FranceSearch for more papers by this authorO. Moudam, O. Moudam Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, FranceSearch for more papers by this authorJ.-F. Nierengarten, J.-F. Nierengarten jfnierengarten@lcc-toulouse.fr Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, FranceSearch for more papers by this authorZ. Zhou, Z. Zhou Philips Research, High Tech Campus 4, 5656 AE Eindhoven, The NetherlandsSearch for more papers by this authorR. T. Wegh, R. T. Wegh rene.wegh@philips.com Philips Research, High Tech Campus 4, 5656 AE Eindhoven, The NetherlandsSearch for more papers by this authorR. Welter, R. Welter Laboratoire DECOMET, Université Louis Pasteur, 4, rue Blaise Pascal 67000 Strasbourg, FranceSearch for more papers by this author N. Armaroli, N. Armaroli armaroli@isof.cnr.it Molecular Photoscience Group, Istituto per la Sintesi Organica e la Fotoreattività del CNR, Via Gobetti 101, 40129 Bologna, ItalySearch for more papers by this authorG. Accorsi, G. Accorsi Molecular Photoscience Group, Istituto per la Sintesi Organica e la Fotoreattività del CNR, Via Gobetti 101, 40129 Bologna, ItalySearch for more papers by this authorM. Holler, M. Holler Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur et CNRS, 25 rue Becquerel, 67087 Strasbourg Cedex 2, FranceSearch for more papers by this authorO. Moudam, O. Moudam Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, FranceSearch for more papers by this authorJ.-F. Nierengarten, J.-F. Nierengarten jfnierengarten@lcc-toulouse.fr Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, FranceSearch for more papers by this authorZ. Zhou, Z. Zhou Philips Research, High Tech Campus 4, 5656 AE Eindhoven, The NetherlandsSearch for more papers by this authorR. T. Wegh, R. T. Wegh rene.wegh@philips.com Philips Research, High Tech Campus 4, 5656 AE Eindhoven, The NetherlandsSearch for more papers by this authorR. Welter, R. Welter Laboratoire DECOMET, Université Louis Pasteur, 4, rue Blaise Pascal 67000 Strasbourg, FranceSearch for more papers by this author First published: 02 February 2006 https://doi.org/10.1002/adma.200502365Citations: 314 † We acknowledge the financial support of the EC through the Integrated Project OLLA (contract no. IST-2002-004607). AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Highly luminescent CuI complexes with one phenanthroline and one (bis[2-(diphenylphosphino)phenyl]ether) ligand show an emission quantum yield of up to 28 % upon deactivation of the metal-to-ligand charge-transfer excited states; their X-ray crystal structure shows a distorted tetrahedral geometry (see figure and inside cover). One of these compounds is used as an active material in a light-emitting electrochemical cell; it exhibits an efficiency similar to that of RuII-type complexes. Citing Literature Volume18, Issue10Special Issue: Supramolecular Approaches to Organic Electronics and NanotechnologyMay, 2006Pages 1313-1316 RelatedInformation
Referência(s)