Decomposition of the t ‐butoxy radical: II. Studies over the temperature range 303—393 K
1989; Wiley; Volume: 21; Issue: 7 Linguagem: Inglês
10.1002/kin.550210705
ISSN1097-4601
AutoresL. Batt, Mohamed Wahab Mohamed Hisham, M. Mackay,
Tópico(s)Spectroscopy and Laser Applications
ResumoAbstract The near U‐V photolysis of t ‐butyl nitrite has been studied over the temperature range 303–393 K. Under these conditions t ‐butyl nitrite was shown to be a very clean photochemical source of t ‐butoxy radicals. This allows a study of the decomposition of the t ‐butoxy radical to be made over this temperature range (3). equation image Extrapolation of the rate constants k 3 to high pressure and combination with our previous thermal data give the results:
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