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Comparative catalytic C–H vs. C–Si activation of arenes with Pd complexes directed by urea or amide groups

2009; Royal Society of Chemistry; Issue: 26 Linguagem: Inglês

10.1039/b905717j

1364-548X

Waqar Rauf, Amber L. Thompson, John M. Brown,

Fluorine in Organic Chemistry

Analysis of regiocontrol in Pd-catalysed C–H activation leads to observations of aryltrimethylsilyl activation and to superior results with urea-based substrates.