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BIBTEX RIS

A Practical and Green Chemical Process: Fluoroalkyldistannoxane-Catalyzed Biphasic Transesterification

2001; Wiley; Volume: 40; Issue: 19 Linguagem: Inglês

10.1002/1521-3773(20011001)40

ISSN

1521-3773

Autores

Jiannan Xiang, Shinji Toyoshima, Akihiro Orita, Junzo Otera,

Tópico(s)

Sulfur-Based Synthesis Techniques

Resumo

There is no need for the recovery of the catalyst in the fluorous biphasic transesterification catalyzed by [{Cl(C6F13CH2CH2)2SnOSn(C6F13CH2CH2)2Cl}2] (1; see scheme), which results in quantitative conversions and yields. An FC-72 solution of the dimeric fluoroalkyldistannoxane 1 can be recycled repeatedly without having to recover the neat catalyst.

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