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Highly Conducting Coordination Polymers Based on Infinite M(4,4′‐bpy) Chains Flanked by Regular Stacks of Non‐Integer TCNQ Radicals

2011; Wiley; Volume: 123; Issue: 41 Linguagem: Inglês

10.1002/ange.201101658

1521-3757

María Ballesteros‐Rivas, Akira Ota, Eric W. Reinheimer, Andrey Prosvirin, J. Valdés-Martı́nez, Kim R. Dunbar,

Metal-Organic Frameworks: Synthesis and Applications

Angewandte ChemieVolume 123, Issue 41 p. 9877-9881 Zuschrift Highly Conducting Coordination Polymers Based on Infinite M(4,4′-bpy) Chains Flanked by Regular Stacks of Non-Integer TCNQ Radicals† Maria Ballesteros-Rivas, Maria Ballesteros-Rivas Instituto de Quimica, UNAM (Mexico)Search for more papers by this authorDr. Akira Ota, Dr. Akira Ota Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorDr. Eric Reinheimer, Dr. Eric Reinheimer Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorDr. Andrey Prosvirin, Dr. Andrey Prosvirin Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorProf. Jesús Valdés-Martinez, Prof. Jesús Valdés-Martinez Instituto de Quimica, UNAM (Mexico)Search for more papers by this authorProf. Kim R. Dunbar, Corresponding Author Prof. Kim R. Dunbar dunbar@mail.chem.tamu.edu Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmDepartment of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this author Maria Ballesteros-Rivas, Maria Ballesteros-Rivas Instituto de Quimica, UNAM (Mexico)Search for more papers by this authorDr. Akira Ota, Dr. Akira Ota Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorDr. Eric Reinheimer, Dr. Eric Reinheimer Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorDr. Andrey Prosvirin, Dr. Andrey Prosvirin Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this authorProf. Jesús Valdés-Martinez, Prof. Jesús Valdés-Martinez Instituto de Quimica, UNAM (Mexico)Search for more papers by this authorProf. Kim R. Dunbar, Corresponding Author Prof. Kim R. Dunbar dunbar@mail.chem.tamu.edu Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmDepartment of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012 (USA) http://www.chem.tamu.edu/rgroup/dunbar/dunbar.htmSearch for more papers by this author First published: 30 August 2011 https://doi.org/10.1002/ange.201101658Citations: 16 † K.R.D. thanks the National Science Foundation (CHE-0957840) and the Welch Foundation (grant A-1449) for support of this work. Financial support for M.F.B.R. by a CONACyT fellowship is gratefully acknowledged. The authors thank Dr. R. A. Toscano for his assistance with X-ray data refinement during the revision stage and G. A. Ballesteros Rivas for his valuable assistance on technical aspects of the work. 4,4′-bpy=4,4′-bipyridine. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Hochgradig leitfähige Koordinationspolymere vom Typ [M(4,4′-bpy)(η1-TCNQ)2(CH3OH)2]TCNQ (M=Mn, Zn) wurden mit TCNQ (7,7,8,8-Tetracyanochinodimethan) als Baustein hergestellt (siehe Bild). Stapel von TCNQ mit regelmäßigen Abständen sind durch zwei η1-TCNQ-Liganden aus einem Stapel mit freien TCNQ-Radikalen mit einem MnII-4,4′-Bipyridin-Rückgrat verbunden. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201101658_sm_miscellaneous_information.pdf682.7 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume123, Issue41October 4, 2011Pages 9877-9881 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation