Artigo Revisado por pares

Coordination of Dimethyl(thionitroso)amine to Pentacarbonylchromium via the Sulfur Atom

1981; Wiley; Volume: 20; Issue: 6-7 Linguagem: Inglês

10.1002/anie.198105912

ISSN

1521-3773

Autores

Herbert W. Roesky, Ralf Emmert, W. Clegg, Wilhelm Isenberg, George M. Sheldrick,

Tópico(s)

Organic Chemistry Cycloaddition Reactions

Resumo

Unstable (1), coordinated to the metal via sulfur and not via nitrogen is the first acyclic sulfur-nitrogen ligand. The 1:1 complex (2) forms stable ruby-red crystals at room temperature.

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