Coordination of Dimethyl(thionitroso)amine to Pentacarbonylchromium via the Sulfur Atom
1981; Wiley; Volume: 20; Issue: 6-7 Linguagem: Inglês
10.1002/anie.198105912
ISSN1521-3773
AutoresHerbert W. Roesky, Ralf Emmert, W. Clegg, Wilhelm Isenberg, George M. Sheldrick,
Tópico(s)Organic Chemistry Cycloaddition Reactions
ResumoUnstable (1), coordinated to the metal via sulfur and not via nitrogen is the first acyclic sulfur-nitrogen ligand. The 1:1 complex (2) forms stable ruby-red crystals at room temperature.
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