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Nanofabrication: Reversible Self‐Assembly of an Imbedded Hexameric Metallomacrocycle within a Macromolecular Superstructure

2005; Wiley; Volume: 44; Issue: 11 Linguagem: Inglês

10.1002/anie.200462379

1521-3773

Pingshan Wang, Charles N. Moorefield, George R. Newkome,

Chemical Synthesis and Analysis

Angewandte Chemie International EditionVolume 44, Issue 11 p. 1679-1683 Communication Nanofabrication: Reversible Self-Assembly of an Imbedded Hexameric Metallomacrocycle within a Macromolecular Superstructure† Pingshan Wang Dr., Pingshan Wang Dr. Departments of Polymer Science and Chemistry, Goodyear Polymer Center, The University of Akron, Akron, OH 44325-4717, USA, Fax: (+1) 330-972-2413Search for more papers by this authorCharles N. Moorefield Dr., Charles N. Moorefield Dr. Maurice Morton Institute of Polymer ScienceSearch for more papers by this authorGeorge R. Newkome Prof. Dr., George R. Newkome Prof. Dr. newkome@uakron.edu Departments of Polymer Science and Chemistry, Goodyear Polymer Center, The University of Akron, Akron, OH 44325-4717, USA, Fax: (+1) 330-972-2413 Maurice Morton Institute of Polymer ScienceSearch for more papers by this author Pingshan Wang Dr., Pingshan Wang Dr. Departments of Polymer Science and Chemistry, Goodyear Polymer Center, The University of Akron, Akron, OH 44325-4717, USA, Fax: (+1) 330-972-2413Search for more papers by this authorCharles N. Moorefield Dr., Charles N. Moorefield Dr. Maurice Morton Institute of Polymer ScienceSearch for more papers by this authorGeorge R. Newkome Prof. Dr., George R. Newkome Prof. Dr. newkome@uakron.edu Departments of Polymer Science and Chemistry, Goodyear Polymer Center, The University of Akron, Akron, OH 44325-4717, USA, Fax: (+1) 330-972-2413 Maurice Morton Institute of Polymer ScienceSearch for more papers by this author First published: 02 March 2005 https://doi.org/10.1002/anie.200462379Citations: 99 † The authors are very thankful for financial support from the Air Force Office of Scientific Research (F49620-02-1-0428), the National Science Foundation (DMR-0196231, DMR-0401780, INT-0405242, CHE-0341701, DMR-0414599, CHE-0420987), the Korea Research Foundation (KRF-2003-042-C00069), and the Ohio Board of Reagents. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Turned inside out: The construction of a peripheral 114-membered macrocycle by a Grubbs-catalyzed metathesis reaction facilitates the self-assembly of a terpyridine-based FeII hexamer. The quantitative, base-promoted removal of the FeII centers allows the reversible disassembly of the metalated complex (see scheme, gray metal). Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462379_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume44, Issue11March 4, 2005Pages 1679-1683 RelatedInformation