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Nitro(nitroso)cyanomethanides

2005; Wiley; Volume: 44; Issue: 25 Linguagem: Inglês

10.1002/anie.200500495

1521-3773

Harald Brand, Péter Mayer, Axel Schulz, Jan J. Weigand,

Magnetism in coordination complexes

More bangs for the buck. Explosive nitro(nitroso)cyanomethanides M′[C(NO2)(NO)(CN)] (M′=alkali metal, NMe4) were prepared in a simple, two-step, high-yielding procedure, fully characterized, and shown to be stable at ambient temperature. The thermal properties were studied, and the structures of several nitro(nitroso)cyanomethanide salts were determined by X-ray diffraction. The structure and bonding in these compounds are discussed on the basis of calculations. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z500495_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.