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BIBTEX RIS

Towards conformationally-locked difluorosugar analogues: an unexpected sense of dihydroxylationElectronic supplementary information (ESI) available: ROESY spectrum of 6b at 223 K. See http://www.rsc.org/suppdata/cc/b3/b313813e/

2004; Royal Society of Chemistry; Issue: 3 Linguagem: Inglês

10.1039/b313813e

ISSN

1364-548X

Autores

John Fawcett, Gerry A. Griffiths, Jonathan M. Percy, Stéphane Pintat, Clive A. Smith, Neil S. Spencer, E. Uneyama,

Tópico(s)

Oxidative Organic Chemistry Reactions

Resumo

Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.

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