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Enzymatic preparation of (3S,6R) and (3R,6S)-3-hydroxy-6-acetoxycyclohex-1-ene

1991; Elsevier BV; Volume: 32; Issue: 32 Linguagem: Inglês

10.1016/0040-4039(91)80595-w

1873-3581

Keith Harris, Qu‐Ming Gu, Yun‐Er Shih, Gary Girdaukas, Charles J. Sih,

Microbial Metabolic Engineering and Bioproduction

Pseudomonas cepacia lipase-catalyzed enantioselective hydrolysis of 2 in water afforded (3S,6R)-3. The antipode (3R,6S)-3 was prepared by enantioselective acylation of 4 using the same enzyme.