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Interconvertible Oligothiophene Nanorods and Nanotapes with High Charge‐Carrier Mobilities

2009; Wiley; Volume: 15; Issue: 37 Linguagem: Inglês

10.1002/chem.200901336

ISSN

1521-3765

Autores

Shiki Yagai, Tetsuro Kinoshita, Yoshihiro Kikkawa, Takashi Karatsu, Akihide Kitamura, Yoshihito Honsho, Shu Seki,

Tópico(s)

Synthesis and Properties of Aromatic Compounds

Resumo

Chemistry – A European JournalVolume 15, Issue 37 p. 9320-9324 Communication Interconvertible Oligothiophene Nanorods and Nanotapes with High Charge-Carrier Mobilities Shiki Yagai Dr., Shiki Yagai Dr. [email protected] Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039 PRESTO (Japan) Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama (Japan)Search for more papers by this authorTetsuro Kinoshita, Tetsuro Kinoshita Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorYoshihiro Kikkawa Dr., Yoshihiro Kikkawa Dr. Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562 (Japan)Search for more papers by this authorTakashi Karatsu Prof. Dr., Takashi Karatsu Prof. Dr. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorAkihide Kitamura Prof. Dr., Akihide Kitamura Prof. Dr. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorYoshihito Honsho, Yoshihito Honsho Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this authorShu Seki Prof. Dr., Shu Seki Prof. Dr. PRESTO (Japan) Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama (Japan) Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this author Shiki Yagai Dr., Shiki Yagai Dr. [email protected] Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039 PRESTO (Japan) Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama (Japan)Search for more papers by this authorTetsuro Kinoshita, Tetsuro Kinoshita Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorYoshihiro Kikkawa Dr., Yoshihiro Kikkawa Dr. Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562 (Japan)Search for more papers by this authorTakashi Karatsu Prof. Dr., Takashi Karatsu Prof. Dr. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorAkihide Kitamura Prof. Dr., Akihide Kitamura Prof. Dr. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan), Fax: (+81) 43-290-3039Search for more papers by this authorYoshihito Honsho, Yoshihito Honsho Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this authorShu Seki Prof. Dr., Shu Seki Prof. Dr. PRESTO (Japan) Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama (Japan) Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this author First published: 14 September 2009 https://doi.org/10.1002/chem.200901336Citations: 57Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Barbarian aggregates: A barbituric acid-functionalized quarterthiophene self-aggregates in aliphatic solvents to form nanorods. Upon addition of a bismelamine receptor, the nanorods are converted into nanotapes, which can be thermally reconverted to nanorods. Nanorods and nanotapes self-organize into hexagonal columnar and multilamellar structures with high hole mobilities (see figure). References 1 1aF. Würthner, Chem. Commun. 2004, 1564– 1579; 1bA. C. Grimsdale, K. Müllen, Angew. Chem. 2005, 117, 5732– 5772; Angew. Chem. Int. Ed. 2005, 44, 5592– 5629; 1cA. P. H. J. Schenning, E. W. Meijer, Chem. Commun. 2005, 3245– 3258; 1dF. J. M. Hoeben, P. Jonkheijm, E. W. Meijer, A. P. H. J. Schenning, Chem. Rev. 2005, 105, 1491– 1546; 1eA. Ajayaghosh, V. K. Praveen, Acc. Chem. Res. 2007, 40, 644– 656; 1fS. Sergeyev, W. Pisula, Y. H. Geerts, Chem. Soc. Rev. 2007, 36, 1902– 1929; 1gJ.-H. Ryu, D.-J. Hong, M. Lee, Chem. Commun. 2008, 1043– 1054; 1hL. Zang, Y. 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Fenniri, B.-L. Deng, E. Ribbe Alexander, K. Hallenga, J. Jacob, P. Thiyagarajan, Proc. Natl. Acad. Sci. USA 2002, 99, 6487– 6492. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description chem_200901336_sm_miscellaneous_information.pdf2.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume15, Issue37September 21, 2009Pages 9320-9324 ReferencesRelatedInformation

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