Synthesis of the Erythrina Alkaloid Erysotramidine
2014; American Chemical Society; Volume: 79; Issue: 17 Linguagem: Inglês
10.1021/jo501583c
ISSN1520-6904
AutoresChloé L’Homme, Marc-André Ménard, Sylvain Canesi,
Tópico(s)Chemical synthesis and alkaloids
ResumoA concise synthesis of erysotramidine (an alkaloid belonging to the erythrina family) was achieved starting with an inexpensive phenol and amine derivative. The synthesis is based on oxidative phenol dearomatizations mediated by a hypervalent iodine reagent and includes a novel route to a key indolinone moiety.
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