Monofluorocarbene and its syn / anti Selectivity
1968; Wiley; Volume: 7; Issue: 10 Linguagem: Inglês
10.1002/anie.196808201
ISSN1521-3773
Autores Tópico(s)Phosphorus compounds and reactions
ResumoAngewandte Chemie International Edition in EnglishVolume 7, Issue 10 p. 820-821 Communication Monofluorocarbene and its syn/anti Selectivity† Priv.-Doz. Dr. M. Schlosser, Priv.-Doz. Dr. M. Schlosser Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Search for more papers by this authorDipl.-Chem. G. Heinz, Corresponding Author Dipl.-Chem. G. Heinz Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Search for more papers by this author Priv.-Doz. Dr. M. Schlosser, Priv.-Doz. Dr. M. Schlosser Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Search for more papers by this authorDipl.-Chem. G. Heinz, Corresponding Author Dipl.-Chem. G. Heinz Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Organisch-Chemisches Institut der Universität, 69 Heidelberg, Tiergartenstrasse (Germany) and Institut für experimentelle Krebsforschung, 69 Heidelberg, Voss-Strasse 3 (Germany)Search for more papers by this author First published: October 1968 https://doi.org/10.1002/anie.196808201Citations: 20 † The authors thank the Fonds der Chemischen Industrie for support of these investigations. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL No abstract is available for this article. References 1 We do not differentiate here between a “free” carbene and its lithium salt adduct (carbenoid). 2 Review: W. Kirmse: Carbene Chemistry, Academic Press, New York 1964. 3 G. L. Closs and R. A. Moss, J. Amer. chem. Soc. 86, 4042 (1964); R. A. Moss and R. Gerstl, Tetrahedron 22, 2637 (1966). 4 Summary: J. A. Ketelaar: Chemische Konstitution. Vieweg, Brunswick 1946, p. 82. 5 G. L. Closs and J. J. Coyle, J. org. Chemistry 31, 2759 (1966). 6 Fluorocarbene is also formed transitorily in the decomposition of some photochemically or radiochemically excited fluorohalogenomethanes and then adds unselectively to olefins (Y. N. Tang andF. S. Rowland, J. Amer. chem. Soc. 89, 6420 (1967); T. Marolewski and N. C. Yang, Chem. Commun. 1967, 1225). 7 “syn” with respect to the position of the chlorine atom in chloro- and chlorofluoro-cyclopropanes and of the fluorine atom in fluorocyclopropanes. 8Cf. M. Schlosser and K. F. Christmann, Liebigs Ann. Chem. 708, 12 (1967). 9 Similar results were obtained on using Br2CHCI in place of CH2Cl2, or Br2CCIF in place of CHCI2F. Citing Literature Volume7, Issue10October 1968Pages 820-821 ReferencesRelatedInformation
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