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CuCrO 2 Delafossite: A Stable Copper Catalyst for Chlorine Production

2013; Wiley; Volume: 52; Issue: 37 Linguagem: Inglês

10.1002/anie.201304254

1521-3773

Amol P. Amrute, Gastón O. Larrazábal, Cecilia Mondelli, Javier Pérez‐Ramírez,

Catalytic Processes in Materials Science

Angewandte Chemie International EditionVolume 52, Issue 37 p. 9772-9775 Communication CuCrO2 Delafossite: A Stable Copper Catalyst for Chlorine Production† Amol P. Amrute, Amol P. Amrute Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorGastón O. Larrazábal, Gastón O. Larrazábal Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorDr. Cecilia Mondelli, Dr. Cecilia Mondelli Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorProf. Javier Pérez-Ramírez, Corresponding Author Prof. Javier Pérez-Ramírez [email protected] Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this author Amol P. Amrute, Amol P. Amrute Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorGastón O. Larrazábal, Gastón O. Larrazábal Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorDr. Cecilia Mondelli, Dr. Cecilia Mondelli Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this authorProf. Javier Pérez-Ramírez, Corresponding Author Prof. Javier Pérez-Ramírez [email protected] Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich (Switzerland)Search for more papers by this author First published: 20 June 2013 https://doi.org/10.1002/anie.201304254Citations: 62 † Bayer MaterialScience AG is acknowledged for permission to publish these results. Dr. Z. Łodziana is thanked for providing the thermodynamic data. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract With time comes wisdom: Since the implementation of CuCl2 for HCl oxidation by Deacon in 1868, the search for stable copper catalysts has been futile. Cuprous delafossite, CuCrO2 (see picture), is shown to have unprecedented stability against chlorination, allowing for durable Cl2 production with no metal loss. Based on this, a highly active CuCrO2-CeO2 composite was developed, a cost-effective Cl2 recovery method. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201304254_sm_miscellaneous_information.pdf478.6 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue37September 9, 2013Pages 9772-9775 RelatedInformation