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Artigo Revisado por pares
BIBTEX RIS

Asymmetric Alkylation of Nitroalkanes

2000; Wiley; Volume: 39; Issue: 17 Linguagem: Inglês

10.1002/1521-3773(20000901)39

ISSN

1521-3773

Autores

Barry M. Trost, Jean‐Philippe Surivet,

Tópico(s)

Chemical Reaction Mechanisms

Resumo

Cyclic meso-2-ene-1,4-diol diesters undergo desymmetrization and cycloalkenyl esters undergo dynamic kinetic asymmetric transformations with excellent enantioselectivity when nitromethane and 2-nitropropane are used in the reaction (see scheme). A short synthesis of carbanucleosides also emerges.

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