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Artigo Revisado por pares
BIBTEX RIS

Palladium‐Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas

2003; Wiley; Volume: 43; Issue: 3 Linguagem: Inglês

10.1002/anie.200352444

ISSN

1521-3773

Autores

Jeffrey T. Bagdanoff, Brian M. Stoltz,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

Air is enough to mediate the highly enantioselective oxidation of secondary alcohols at room temperature with palladium(II) and sparteine in nonflammable solvents. Examination of the role of solvents capable of hydrogen bonding and their ability to solvate halide anions led to a novel set of conditions for the highly enantioselective oxidative kinetic resolution of secondary alcohols.

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