Portal de Periódicos da CAPES

Phase Equilibria in the System SrO‐CdO‐V 2 O 5

1972; Wiley; Volume: 55; Issue: 10 Linguagem: Inglês

10.1111/j.1151-2916.1972.tb13415.x

1551-2916

Jesse J. Brown,

Radioactive element chemistry and processing

Phase equilibria in the system SrO‐CdO‐V 2 O 5 in air were established from data obtained by DTA, quenching, and high‐temperature solid‐state reaction experiments. The SrO‐V 2 O 5 boundary system contains 4 compounds at SrO to V 2 O 5 molar ratios of 4:1, 3:1, 2:1, and 1:1. A fifth compound with a molar composition of ∼10:3 with the apatite crystal structure was also found; it may, however, be a hydroxyapatite phase. The CdO‐V 2 O 5 system contains the compounds 3CdO·V 2 O 5 , 2CdO·V 2 O 5 , and CdO·V 2 O 5 . The latter compound exhibits a rapid reversible polymorphic transition at 180°C. Complete solid solubility exists in the SrO‐CdO system. The most probable compatibility relations were determined from the data available for the SrO‐CdO‐V 2 O 5 ternary system. Limited solid solubility exists between SrO·V 2 O 5 and CdO·V 2 O 5 , and the high‐temperature CdO·V 2 O 5 polymorph is stabilized to room temperature by solid solution of SrO·V 2 O 5 . Evidence for the existence of 2 ternary compounds with limited local solid solubility is also presented.