trans-[Fe(CN)4(CO)2]2−, a 21st Century [Fe(CN)(CO)] Compound
2001; Wiley; Volume: 40; Issue: 14 Linguagem: Inglês
10.1002/1521-3773(20010716)40
ISSN1521-3773
AutoresJianfeng Jiang, Stephen A. Koch,
Tópico(s)CO2 Reduction Techniques and Catalysts
ResumoAngewandte Chemie International EditionVolume 40, Issue 14 p. 2629-2631 Communication trans-[Fe(CN)4(CO)2]2−, a 21st Century [Fe(CN)(CO)] Compound Jianfeng Jiang, Jianfeng Jiang Department of Chemistry State University of New York at Stony Brook Stony Brook, NY 11794-3400 (USA) Fax: (+1) 631-632-7960Search for more papers by this authorStephen A. Koch Prof., Stephen A. Koch Prof. [email protected] Department of Chemistry State University of New York at Stony Brook Stony Brook, NY 11794-3400 (USA) Fax: (+1) 631-632-7960Search for more papers by this author Jianfeng Jiang, Jianfeng Jiang Department of Chemistry State University of New York at Stony Brook Stony Brook, NY 11794-3400 (USA) Fax: (+1) 631-632-7960Search for more papers by this authorStephen A. Koch Prof., Stephen A. Koch Prof. [email protected] Department of Chemistry State University of New York at Stony Brook Stony Brook, NY 11794-3400 (USA) Fax: (+1) 631-632-7960Search for more papers by this author First published: 10 July 2001 https://doi.org/10.1002/1521-3773(20010716)40:14 3.0.CO;2-YCitations: 40 This work was supported by a National Institutes of Health Grant (GM 58000). We thank Professors Michelle Millar and Albert Haim for discussion. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract In 1887, more than a century after the synthesis of [FeII(CN)6]4−, the complex [FeII(CN)5(CO)]3−, in which a CN− ligand is replaced by CO, was reported. It has taken an additional century for the synthesis of the complex in which a second CN− ligand is substituted by CO: trans-[FeII(CN)4(CO)2]2− (structure shown). Remarkably, this anion is prepared by the simple reaction of FeCl2 with NaCN and CO in water. [Fe(CN)x(CO)y] complexes are of interest as models for the active site of hydrogenase enzymes. References 1 J. A. Muller, C. R. Hebd. Seances Acad. Sci. 1887, 104, 992; Web of Science®Google Scholar Gmelin, Vol. 36B, 1976, p. 24. Google Scholar 2 S. A. Goldfield, K. N. Raymond, Inorg. Chem. 1974, 13, 770. 10.1021/ic50134a002 CASWeb of Science®Google Scholar 3 The [Fe(CN)(CO)4Fe(CO)4]− dimer has also been synthesized: J. K. Ruff, Inorg. 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