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Asymmetric Reduction Using Lithium Aluminum Hydride Modified with Chiral Ligand Prepared from (1 R )‐(‐)‐Myrtenol

1994; Wiley; Volume: 41; Issue: 2 Linguagem: Inglês

10.1002/jccs.199400030

2192-6549

Ta‐Jung Lu, Shew‐Wen Liu,

Analytical Chemistry and Chromatography

Abstract The reduction of prochiral ketones with a chiral reducing reagent, prepared from lithium aluminum hydride and (1R,2S,3S,5R)‐(‐)‐10‐methoxypinanediol (2), produced secondary chiral alcohols in good chemical yields (57–98%) and moderate enantiomeric excess (8–72%).