Archimedean solids: Transition metal mediated rational self-assembly of supramolecular-truncated tetrahedra
2000; National Academy of Sciences; Volume: 97; Issue: 4 Linguagem: Inglês
10.1073/pnas.030264697
ISSN1091-6490
AutoresStefan Leininger, Jun Fan, M. Schmitz, Peter J. Stang,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoA family of nanoscale-sized supramolecular cage compounds with a polyhedral framework is prepared by self-assembly from tritopic building blocks and rectangular corner units via noncovalent coordination interactions. These highly symmetrical cage compounds are described as face-directed, self-assembled truncated tetrahedra with T(d) symmetry.
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