Portal de Periódicos da CAPES

Molecule-induced homolysis of N-hydroxyphthalimide (NHPI) by peracids and dioxirane. A new, simple, selective aerobic radical epoxidation of alkenes

2006; Elsevier BV; Volume: 47; Issue: 9 Linguagem: Inglês

10.1016/j.tetlet.2005.12.089

1873-3581

Francesco Minisci, Cristian Gambarotti, Monica Pierini, Ombretta Porta, Carlo Punta, Francesco Recupero, Massimo Lucarini, Verónica Mugnaini,

Radical Photochemical Reactions

Evidences are reported concerning the molecule-induced homolysis of NHPI by peracids and dioxirane; their combination can be utilized for the aerobic free-radical epoxidation of alkenes with selectivity quite different from the well-known epoxidation by peracids.