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A Highly Connected Porous Coordination Polymer with Unusual Channel Structure and Sorption Properties

2009; Wiley; Volume: 48; Issue: 29 Linguagem: Inglês

10.1002/anie.200901964

1521-3773

Yue‐Biao Zhang, Wei‐Xiong Zhang, Fei‐Yue Feng, Jie‐Peng Zhang, Xiao‐Ming Chen,

Polyoxometalates: Synthesis and Applications

Abstract Making connections : A hydroxy‐centered trinuclear nickel cluster has been employed to construct a highly connected, highly symmetric framework with a uninodal nine‐connected topology. An array of triakis tetrahedra leads to a biporous intersecting‐channel system (see picture). magnified image