Portal de Periódicos da CAPES

Synthesis of poly( m ‐phenyleneisophthalamide) by solid‐state polycondensation of isophthalic acid with m ‐phenylenediamine

2011; Wiley; Volume: 49; Issue: 22 Linguagem: Inglês

10.1002/pola.24934

1099-0518

Cenyao Zhang, Yu Shoji, Tomoya Higashihara, Akimitsu Tsukuda, Takashi Ochi, Mitsuru Ueda,

Conducting polymers and applications

Journal of Polymer Science Part A: Polymer ChemistryVolume 49, Issue 22 p. 4725-4728 Rapid Communication Synthesis of poly(m-phenyleneisophthalamide) by solid-state polycondensation of isophthalic acid with m-phenylenediamine Cenyao Zhang, Cenyao Zhang Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorYu Shoji, Yu Shoji Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorTomoya Higashihara, Tomoya Higashihara Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorAkimitsu Tsukuda, Akimitsu Tsukuda Films & Film Products Research Laboratories, Toray Industries, Inc., 1-1-1, Sonoyama, Otsu, Shiga 520-8558, JapanSearch for more papers by this authorTakashi Ochi, Takashi Ochi Technology Center, Toray Industries, Inc., 1-1-1, Sonoyama, Otsu, Shiga 520-8558, JapanSearch for more papers by this authorMitsuru Ueda, Corresponding Author Mitsuru Ueda ueda.m.ad@m.titech.ac.jp Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanDepartment of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this author Cenyao Zhang, Cenyao Zhang Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorYu Shoji, Yu Shoji Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorTomoya Higashihara, Tomoya Higashihara Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this authorAkimitsu Tsukuda, Akimitsu Tsukuda Films & Film Products Research Laboratories, Toray Industries, Inc., 1-1-1, Sonoyama, Otsu, Shiga 520-8558, JapanSearch for more papers by this authorTakashi Ochi, Takashi Ochi Technology Center, Toray Industries, Inc., 1-1-1, Sonoyama, Otsu, Shiga 520-8558, JapanSearch for more papers by this authorMitsuru Ueda, Corresponding Author Mitsuru Ueda ueda.m.ad@m.titech.ac.jp Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanDepartment of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-H120, O-okayama, Meguro-ku, Tokyo 152-8552, JapanSearch for more papers by this author First published: 27 August 2011 https://doi.org/10.1002/pola.24934Citations: 13Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The synthesis of poly(m-phenyleneisophthalamide) was performed by thermal solid-phase polymerization from isophthalic acid and m-phenylenediamine without using any solvents or condensation agents. The two-stage heating process was conducted. The oligo(m-phenyleneisophthalamide) was first synthesized at a relatively low temperature (260 °C for 1 h), followed by the polycondensation at 400 °C for 1 min under reduced pressure to produce the aramid with an inherent viscosity of 0.55 dL/g. Citing Literature Supporting Information Additional Supporting Information may be found in the online version of this article. Filename Description POLA_24934_sm_SuppFigs.doc173.5 KB Supporting Information Figures. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue2215 November 2011Pages 4725-4728 RelatedInformation