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Development of a Ruthenium‐Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant

2004; Wiley; Volume: 43; Issue: 39 Linguagem: Inglês

10.1002/anie.200460528

1521-3773

Man Kin Tse, Christian Döbler, Santosh Bhor, Markus Klawonn, Wolfgang Mägerlein, Herbert Hugl, Matthias Beller,

Oxidative Organic Chemistry Reactions

Angewandte Chemie International EditionVolume 43, Issue 39 p. 5255-5260 Communication Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant† Man Kin Tse Dr., Man Kin Tse Dr. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorChristian Döbler Dr., Christian Döbler Dr. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorSantosh Bhor Dipl.-Chem., Santosh Bhor Dipl.-Chem. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorMarkus Klawonn Dipl.-Chem., Markus Klawonn Dipl.-Chem. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorWolfgang Mägerlein Dr., Wolfgang Mägerlein Dr. Bayer AG, 51368 Leverkusen, GermanySearch for more papers by this authorHerbert Hugl Dr., Herbert Hugl Dr. Bayer AG, 51368 Leverkusen, GermanySearch for more papers by this authorMatthias Beller Prof. Dr., Matthias Beller Prof. Dr. matthias.beller@ifok.uni-rostock.de Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this author Man Kin Tse Dr., Man Kin Tse Dr. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorChristian Döbler Dr., Christian Döbler Dr. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorSantosh Bhor Dipl.-Chem., Santosh Bhor Dipl.-Chem. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorMarkus Klawonn Dipl.-Chem., Markus Klawonn Dipl.-Chem. Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this authorWolfgang Mägerlein Dr., Wolfgang Mägerlein Dr. Bayer AG, 51368 Leverkusen, GermanySearch for more papers by this authorHerbert Hugl Dr., Herbert Hugl Dr. Bayer AG, 51368 Leverkusen, GermanySearch for more papers by this authorMatthias Beller Prof. Dr., Matthias Beller Prof. Dr. matthias.beller@ifok.uni-rostock.de Leibniz-Institut für Organische Katalyse (IfOK), Universität Rostock e.V. Buchbinderstrasse 5–6, 18055 Rostock, Germany, Fax: (+49) 381-466-9324Search for more papers by this author First published: 29 September 2004 https://doi.org/10.1002/anie.200460528Citations: 145 † This work has been financed by the State of Mecklenburg-Western Pommerania, the Bundesministerium für Bildung und Forschung (BMBF), and the Deutsche Forschungs. M.K.T. thanks the Alexander von Humboldt Stiftung for granting him an AvH-fellowship. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Novel pyboxazines and the known pybox ligands are used in the ruthenium-catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460528_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume43, Issue39October 4, 2004Pages 5255-5260 RelatedInformation